Intensity of the long-wavelength UV transition of vitamin E

Authors
Citation
B. Vidal, Intensity of the long-wavelength UV transition of vitamin E, CHEM PAP-CH, 55(1), 2001, pp. 7-14
Citations number
25
Categorie Soggetti
Chemistry
Journal title
CHEMICAL PAPERS-CHEMICKE ZVESTI
ISSN journal
03666352 → ACNP
Volume
55
Issue
1
Year of publication
2001
Pages
7 - 14
Database
ISI
SICI code
0366-6352(2001)55:1<7:IOTLUT>2.0.ZU;2-W
Abstract
The intensity of the long-wavelength UV transition of tocopherols is invest igated using the interaction vector model. Intensity of alpha -tocopherol i s the lowest of the series because it is the molecule which allows the most efficiently the effects of the alkyl groups to oppose the effects on inten sity of the two alkoxy-like groups (a hydroxy group and a fused trimethylen eoxy moiety). Intensity of eta -tocopherol is the highest because the only methyl substituent cannot attenuate the effects of the alkoxy-like groups.