Synthesis of titanium(IV) complexes with Schiff-base ligand and their catalytic activities for polymerization of ethylene and styrene

Authors
Yong, L Huang, JL Lian, B Qian, YL
Citation
L. Yong et al., Synthesis of titanium(IV) complexes with Schiff-base ligand and their catalytic activities for polymerization of ethylene and styrene, CHIN J CHEM, 19(4), 2001, pp. 429-432
Citations number
24
Categorie Soggetti
Chemistry
Journal title
CHINESE JOURNAL OF CHEMISTRY
ISSN journal
1001604X → ACNP
Volume
19
Issue
4
Year of publication
2001
Pages
429 - 432
Database
ISI
SICI code
1001-604X(200104)19:4<429:SOTCWS>2.0.ZU;2-Z
Abstract
Reaction of titanium(IV) isopropoxide with the unusual kind of Shiff-base i n 1:1 molar ratio gives a variety of new derivatives of titanium(IV) In hig h yield. These complexes were characterized by elemental analyses, IR, MS a nd H-1 MMR. It was noteworthy to find that all these complexes were active for polymerizations of ethylene and styrene when activated by a Lewis acid cocatalyst (MAO).