Mixed surfactant templating route for mesoporous silica

Citation
Lr. Dai et al., Mixed surfactant templating route for mesoporous silica, COLL SURF A, 181(1-3), 2001, pp. 151-157
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
ISSN journal
09277757 → ACNP
Volume
181
Issue
1-3
Year of publication
2001
Pages
151 - 157
Database
ISI
SICI code
0927-7757(20010615)181:1-3<151:MSTRFM>2.0.ZU;2-#
Abstract
Mesoporous silica SBA-3 was synthesized by using mixtures of cationic surfa ctant cetyltrimethylammonium bromide (CTAB), and six nonionic surfactants c ontaining polyoxyethylene as template. The results show, that either by cha nging the ratio of nonionic to cationic surfactant in the mixture, or by in creasing the non-polar chain length of the nonionic surfactants, the pore s ize can be controlled and the mesoporous silica with larger pore size than that synthesized by using CTAB alone as template can be obtained. The short coming of less ordered pore array in the mesoporous silica synthesized by u sing nonionic surfactant alone as template can also be overcome. Mesoporous silica MCM-48 was also synthesized by using CTAB-CnNH2 (n = 8,10,12,14) as template in basic medium. It is revealed that the transition from cubic to lamellar structure takes place with increasing chain length of alkylamine. The effect of non-polar and polar organic additives on d-spacing of silica SBA-3 for CTAB template system was investigated. (C) 2001 Elsevier Science B.V. All rights reserved.