A vibrational spectroscopic study of lithium triflate in polyphosphazenes with linear oligoethyleneoxy side-chains of different lengths

A comparative vibrational spectroscopy study is reported for a series of po lymer electrolytes composed of poly(oligoethyleneoxy phosphazenes) containi ng dissolved lithium triflate. These polymers, of the form [NP((OCH2CH2)(x) OCH3)(2)](n), with x = 0, 1, 2, or 5, have been mixed with LiCF3SO3 in oxyg en:lithium concentration ratios ranging from 10:1 to 40:1. Raman vibrationa l spectroscopy has been used to examine ionic association and local changes of the polymer as the salt concentration and the length of the ethylene ox ide side-chains vary. The degree of ionic association of the triflate ion i ncreases with increasing salt concentration. At a given salt concentration, the degree of ionic association and the nature of the ion-polymer interact ion are dependent on the length of the side-chains. (C) 2001 Elsevier Scien ce Ltd. All rights reserved.