N-methyl-N-alkylpyrrolidinium tetrafluoroborate salts: ionic solvents and solid electrolytes

A series of N-methyl-N-alkylpyrrolidinium tetrafluoroborate salts were synt hesised. The spectroscopic, physical and electrochemical characteristics of this family of salts have been investigated with respect to potential usag e as ionic solvents and electrolytes. The lowest melting point among the fa mily is 64 degreesC for the N-methyl-N-propylpyrrolidinium tetrafluoroborat e (P13BF4). This is sufficiently low to enable this salt to be useful as an ionic liquid in chemical synthesis involving reactions above 70 degreesC. Most of the compounds exhibit one or more solid-solid transitions below the melting point, this behaviour is thought to indicate the existence of plas tic crystal phases. (C) 2001 Elsevier Science Ltd. All rights reserved.