A zinc hydroxide complex of relevance to 5-aminolevulinate dehydratase: The synthesis, structure and reactivity of the tris(2-mercapto-1-phenylimidazolyl)hydroborato complex [Tm-Ph]ZnOH

Authors
Bridgewater, BM Parkin, G
Citation
Bm. Bridgewater et G. Parkin, A zinc hydroxide complex of relevance to 5-aminolevulinate dehydratase: The synthesis, structure and reactivity of the tris(2-mercapto-1-phenylimidazolyl)hydroborato complex [Tm-Ph]ZnOH, INORG CH C, 4(3), 2001, pp. 126-129
Citations number
33
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
4
Issue
3
Year of publication
2001
Pages
126 - 129
Database
ISI
SICI code
1387-7003(200103)4:3<126:AZHCOR>2.0.ZU;2-7
Abstract
The tris(2-mercapto-1-phenylimidazolyl)hydroborato ligand, [Tm-Ph], has bee n used to prepare [Tm-Ph]ZnOH, the first structurally characterized termina l zinc hydroxide complex of a tridentate sulfur donor ligand; as such. [Tm- Ph]ZnOH represents a good structural model for the zinc enzyme 5-aminolevul inate dehydratase(ALAD). (C) 2001 Elsevier Science B.V. All rights reserved .