The synthesis and structure of nickel(II) and copper(II) complexes with N,N-dimethyl-N '-(2, 4-dichlorophenoxy)acetyl hydrazine

Authors
Shulgin, VF Pevzner, NS Zub, VY Strizhakova, NG Maletin, YA
Citation
Vf. Shulgin et al., The synthesis and structure of nickel(II) and copper(II) complexes with N,N-dimethyl-N '-(2, 4-dichlorophenoxy)acetyl hydrazine, INORG CH C, 4(3), 2001, pp. 134-137
Citations number
8
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
4
Issue
3
Year of publication
2001
Pages
134 - 137
Database
ISI
SICI code
1387-7003(200103)4:3<134:TSASON>2.0.ZU;2-G
Abstract
The first examples of nickel(II) and copper(II) complexes derived from unsy mmetrical N,N-dimethylhydrazine have been obtained and studied using both s pectroscopic and X-ray analyses. Square planar copper(II) coordination is s lightly distorted with two trans dimethylamino and two trans imidole-oxygen donor groups. Any extra coordination due to other donor centers is hindere d by methyl groups whose carbon atoms are located at a distance of 2.837-2. 918 Angstrom from the central ion. (C) 2001 Elsevier Science B.V. All right s reserved.