XANES and EXAFS investigations of bonding and structure of Ni and Co derivatives from Prussian Blue coordination compounds

Authors
Hallmeier, KH Sauter, S Szargan, R
Citation
Kh. Hallmeier et al., XANES and EXAFS investigations of bonding and structure of Ni and Co derivatives from Prussian Blue coordination compounds, INORG CH C, 4(3), 2001, pp. 153-156
Citations number
7
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
4
Issue
3
Year of publication
2001
Pages
153 - 156
Database
ISI
SICI code
1387-7003(200103)4:3<153:XAEIOB>2.0.ZU;2-C
Abstract
The oxidation states of the transition metals in the chemically prepared ni ckel and cobalt Prussian White analoga Na2M[Fe(CN)(6)] and K2M[Fe(CN)(6)] a s well as in the Prussian Blue analoga KM[Fe(CN)(6)] (M = Ni, Co) are inves tigated by analyzing the K-edge XANES and EXAFS spectra of the transition m etals excited with synchrotron radiation. These similar substances exhibit different behavior depending on the insertion of nickel or cobalt. Structur al data as derived from the EXAFS measurements are given. (C) 2001 Elsevier Science B.V. All rights reserved.