The first catena-trihydrogen triphosphide: synthesis and crystal structureof [Na(NH3)(5)][Na(NH3)(3)(P3H3)]

Authors
Korber, N Aschenbrenner, J
Citation
N. Korber et J. Aschenbrenner, The first catena-trihydrogen triphosphide: synthesis and crystal structureof [Na(NH3)(5)][Na(NH3)(3)(P3H3)], J CHEM S DA, (8), 2001, pp. 1165-1166
Citations number
11
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
14727773 → ACNP
Issue
8
Year of publication
2001
Pages
1165 - 1166
Database
ISI
SICI code
1472-7773(2001):8<1165:TFCTSA>2.0.ZU;2-X
Abstract
The reaction of P-4 with sodium in liquid ammonia (P : Na ratio 3 : 5) yiel ds crystalline NaNH2 and [Na(NH3)(5)][Na(NH3)(3)(P3H3)], which contains all -trans catena-P3H32- stabilised in the ion complex [Na(NH3)(3)(P3H3)](-).