Assembly of a twin-cage complex containing a linear array of Pd-3

Authors
Liu, HK Su, CY Qian, CM Liu, J Tan, HY Kang, BS
Citation
Hk. Liu et al., Assembly of a twin-cage complex containing a linear array of Pd-3, J CHEM S DA, (8), 2001, pp. 1167-1168
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
14727773 → ACNP
Issue
8
Year of publication
2001
Pages
1167 - 1168
Database
ISI
SICI code
1472-7773(2001):8<1167:AOATCC>2.0.ZU;2-Z
Abstract
The M3L4 twin-cage complex [Pd-3(bitmb)(4)Cl-4]Cl-2. 2H(2)O . CH3CN [bitmb = 1,3-bis(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene] was obtained by asse mbly of three Pd(II) ions with four molecules of the new flexible ditoptic ligand bitmb; structural analysis showed that the complex contains two M2L2 cages with a cavity size of ca. 200 Angstrom (3).