Titanium complexes incorporating bicyclic guanidinate ligands. Structure of a novel titanium-aluminium complex

Authors
Coles, MP Hitchcock, PB
Citation
Mp. Coles et Pb. Hitchcock, Titanium complexes incorporating bicyclic guanidinate ligands. Structure of a novel titanium-aluminium complex, J CHEM S DA, (8), 2001, pp. 1169-1171
Citations number
27
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
14727773 → ACNP
Issue
8
Year of publication
2001
Pages
1169 - 1171
Database
ISI
SICI code
1472-7773(2001):8<1169:TCIBGL>2.0.ZU;2-S
Abstract
Synthetic routes to titanium complexes incorporating the bicyclic guanidina te, 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidinate, [hpp](-), are des cribed; the first example of a chelating coordination mode for the [hpp](-) anion and the trimetallic complex [Me2Al(hpp)(2)TiCl2. AlMe3] containing [ hpp](-) ligands that chelate to titanium and, in addition, bridge to an AlM e2 unit via nitrogen are reported.