Tetrakis(4-aminopyridine)diisothiocyanatonickel(II) and its clathrates with EtOH, Me2CO and DMSO: structures, thermal stabilities and guest exchange

Authors
Nassimbeni, LR Kilkenny, ML
Citation
Lr. Nassimbeni et Ml. Kilkenny, Tetrakis(4-aminopyridine)diisothiocyanatonickel(II) and its clathrates with EtOH, Me2CO and DMSO: structures, thermal stabilities and guest exchange, J CHEM S DA, (8), 2001, pp. 1172-1175
Citations number
13
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
14727773 → ACNP
Issue
8
Year of publication
2001
Pages
1172 - 1175
Database
ISI
SICI code
1472-7773(2001):8<1172:TAICW>2.0.ZU;2-T
Abstract
The structures of the Werner complex, Ni(NCS)(2)(4-NH2-py)(4) as the apohos t, 1, and its inclusion compounds with EtOH/Me2CO, 2, and DMSO, 3, have bee n elucidated. The dynamics of guest exchange between the clathrates have be en monitored by DSC. The inclusion compounds can be formed by exposing the host to vapour of the guest, and powder XRD shows this reaction to be fully reversible.