Recent trends toward smaller diameter in fine copper wire and smaller thick
ness in relied copper foil require improvement in workability of materials.
Generally, workability can be estimated by the strain hardening exponent o
btained from the true stress-true strain curve in the tensile test.
In this work, work hardening behavior of three kinds of recrystallized comm
ercial pure coppers was investigated, The effect of the increase in the ann
ealing temperature is summarized as follows.
(1) In oxygen free copper, the flow stress increases due to the locking har
dening by sulfur, but the strain hardening exponent does not change,
(2) In phosphorus deoxidized copper, the flow stress decreases and the stra
in hardening exponent increases due to phosphorus in the solid solution.
(3) In electrolytic tough pitch copper, the flow stress decreases due to th
e coarsening of Cu2O particles and the strain hardening exponent increases
due to oxygen in solid solution.
The difference in work hardening behavior between three kinds of commercial
ly pure coppers seems to be brought about by the difference in the interact
ion between dislocations or stacking faults and atoms of the above trace el
ements.