An experimental study was performed for the recovery of CO2 from flue gas o
f the electric power plant by pressure swing adsorption process. Activated
carbon was used as an adsorbent. The equilibrium adsorption isotherms of pu
re component and breakthrough curves of their mixture (CO2: N-2: O-2=17 : 7
9 : 4 vol%) were measured. pressure equalization step and product purge ste
p were added to basic 4-step PSA fur the recovery of strong adsorbates. Thr
ough investigation of the effects of each step and total feed rate, highly
concentrated CO2 could be obtained by increasing the adsorption time, produ
ct purge time, and evacuation time simultaneously with full pressure-equali
zation. Based on the basic results, the 3-bed, 8-step PSA cycle with the pr
essure equalization and product purge step was organized. Maximum product p
urity of CO2 was 99.8% and recovery was 34%.