A phenomenological model for the undulating twist grain boundary-C* phase

Citation
Pa. Pramod et al., A phenomenological model for the undulating twist grain boundary-C* phase, LIQ CRYST, 28(4), 2001, pp. 525-533
Citations number
34
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
LIQUID CRYSTALS
ISSN journal
02678292 → ACNP
Volume
28
Issue
4
Year of publication
2001
Pages
525 - 533
Database
ISI
SICI code
0267-8292(200104)28:4<525:APMFTU>2.0.ZU;2-P
Abstract
We propose a simple phenomenological model which is able to account for the various twist grain boundary (TGB) phases, including the recently discover ed undulating twist grain boundary-C* (UTGB(C)*) phase. In the UTGB(C)* pha se, the smectic C* (SmC*)-like blocks and the grain boundaries separating t hem undulate to form a two-dimensional square lattice perpendicular to the TGB helix axis. We treat the grain boundaries separating adjacent smectic b locks as interfaces with an anisotropic interfacial tension. At moderate ch iral strengths we find a TGB(A)-TGB(C)-SmC* sequence. As the chiral strengt h is increased this goes to the sequence TGB(A)-UTGB(C)*-SmC*. Such sequenc es have been observed experimentally.