Optical properties of short pitch cholesteric liquid crystals

Citation
S. Ponti et al., Optical properties of short pitch cholesteric liquid crystals, LIQ CRYST, 28(4), 2001, pp. 591-598
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
LIQUID CRYSTALS
ISSN journal
02678292 → ACNP
Volume
28
Issue
4
Year of publication
2001
Pages
591 - 598
Database
ISI
SICI code
0267-8292(200104)28:4<591:OPOSPC>2.0.ZU;2-B
Abstract
The optical properties of short pitch cholesteric liquid crystals are theor etically analysed in the framework of an effective medium theory. It is sho wn that such properties are well described by a very simple homogeneous mod el, defined by an effective permittivity tensor <(<epsilon>)over tilde> hav ing uniaxial symmetry, that is expanded in a power series of the ratio p/la mbda (o) between the helix pitch and the light wavelength. The linear term is identically zero. This fact gives short pitch cholesterics very unusual properties for their optical activity, which is related to the scaling term s as (p/lambda (o))(m),with m odd and greater than 1. Some problems related to the presence of these terms and concerning boundary effects are discuss ed but not fully resolved. The limits of validity of the different approxim ations, obtained by considering only a limited number of terms, are also fo und.