This article reviews the strengthening and fracture mechanisms that operate
in carbon and low-alloy carbon steels with martensitic microstructures tem
pered at low temperatures, between 150 degreesC and 200 degreesC. The carbo
n-dependent strength of low-temperature-tempered (LTT) martensite is shown
to be a function of the dynamic strain hardening of the dislocation and tra
nsition carbide substructure of martensite crystals. In steels containing u
p to 0.5 mass pet carbon, fracture occurs by ductile mechanisms of microvoi
d formation at dispersions of second-phase particles in the matrix of the s
train-hardened tempered martensite. Steels containing more than 0.5 mass pe
t carbon with LTT martensitic microstructures are highly susceptible to bri
ttle intergranular fracture at prior austenite grain boundaries. The mechan
isms of the intergranular fracture are discussed, and approaches that have
evolved to minimize such fracture and to utilize the high strength of high-
carbon hardened steels are described.