K. Campbell et al., Rigid, cross-conjugated macrocycles: A cyclic alternative to 4,4 '-bipyridines in supramolecular chemistry, ORG LETT, 3(7), 2001, pp. 1045-1048
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The synthesis of two fully conjugated, rigid macrocyclic analogues to 4,4'-
bipyridine is described. The use of these macrocycles in self assembly proc
esses is demonstrated by axial coordination to metalloporphyrins, and one s
ystem (R = Me) has been characterized by single-crystal X-ray crystallograp
hy.