A xanthate transfer radical process for the introduction of the trifluoromethyl group

Authors
Bertrand, F Pevere, V Quiclet-Sire, B Zard, SZ
Citation
F. Bertrand et al., A xanthate transfer radical process for the introduction of the trifluoromethyl group, ORG LETT, 3(7), 2001, pp. 1069-1071
Citations number
26
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
3
Issue
7
Year of publication
2001
Pages
1069 - 1071
Database
ISI
SICI code
1523-7060(20010405)3:7<1069:AXTRPF>2.0.ZU;2-L
Abstract
[GRAPHICS] S-Trifluoromethyl xanthates efficiently add to unactivated alkenes by a rad ical mechanism to give adducts with a trifluoromethyl group at the least hi ndered terminus of the olefin.