Silicon carbide (SiC) coatings and films have been prepared for the first t
ime by electrostatic atomization of a solution of a polymeric precursor and
deposition on to alumina and zirconia substrates. The deposits were heated
to 1300 degreesC prior to their examination by X-ray energy-dispersive spe
ctra and selected-area diffraction in scanning and transmission electron mi
croscopes. The results show that these coatings and films are crystalline a
nd probably consist of co-existing alpha -SiC and beta -SiC phases.