Understanding the passive reaction of two chemical species in shear-free tu
rbulence with order unity Schmidt number is important in atmospheric and tu
rbulent combustion research. The canonical configuration considered here is
the reacting scalar mixing layer; in this problem two initially separated
species mix and react downstream of a turbulence generating grid in a wind
tunnel. A conserved scalar in this flow is, with some restrictions, analogo
us to temperature in a thermal mixing layer, and considerable laboratory da
ta are available on the latter. In this paper, results are reported from hi
gh resolution, direct numerical simulations in which the evolution of the c
onserved scalar field accurately matches that of the temperature field in e
xisting laboratory experiments. Superimposed on the flow are passive, singl
e-step reactions with a wide range of activation energies and stoichiometri
c ratios (r). The resulting data include species concentrations as a functi
on of three spatial dimensions plus time, and statistical moments and spect
ra of all species. Several aspects of the flow are investigated here with t
he conclusions that (1) reactions in which r not equal1 are more accurately
modeled by frozen and equilibrium chemistry limits than are reactions in w
hich r=1, (2) an existing definition of a reduced Damkohler number that inc
ludes temperature and stoichiometry effects is a useful measure of reaction
rate, and (3) existing theoretical models for predicting the coherence and
phase of fuel-oxidizer cross-spectra and the spectrum of the equilibrium f
uel mass fraction when r=1 yield accurate predictions. (C) 2001 American In
stitute of Physics.