Phase structure, processability, and mechanical properties of Rodrun liquid crystalline 5000/Rodrun liquid crystalline 3000 blends

Citation
Fj. Vallejo et al., Phase structure, processability, and mechanical properties of Rodrun liquid crystalline 5000/Rodrun liquid crystalline 3000 blends, POLYM J, 33(2), 2001, pp. 128-132
Citations number
25
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
POLYMER JOURNAL
ISSN journal
00323896 → ACNP
Volume
33
Issue
2
Year of publication
2001
Pages
128 - 132
Database
ISI
SICI code
0032-3896(2001)33:2<128:PSPAMP>2.0.ZU;2-7
Abstract
New Liquid crystalline materials with low processing temperature, whilst ma intaining the mechanical properties characteristic of the liquid crystallin e polymers, were sought by blending Rodrun 5000 and Rodrun 3000. After dire ct injection moulding, the solid blends appeared as miscible. The crystalli zation from the melt was hindered by the presence of the other component, b ut the minimum processing temperature of Rodrun 5000 clearly decreased as a consequence of the presence of Rodrun 3000. This decrease was not at the c ost of a decrease in the overall mechanical properties. It should be noted that, unlike in thermoplastics blends, in liquid crystal polymer (LCP) blen ds the miscibility level influences the modulus values. Immiscibility leads to clear positive synergisms in the values of the modulus of elasticity an d also in the tensile strength, that are not seen in miscible LCP blends.