The effect of gamma -irradiation on positronium (Ps) formation, especially
the decrement of Ps formation at room temperature, was studied in linear po
ly(ethylene). We found that chemical changes, such as oxidation, cross-link
ing, or radicals created by gamma -irradiation of similar to 50 kGy do not
affect Ps formation very much. The decrement of Ps formation was probably c
aused by a temporary change of physical structure by irradiation that disap
pears by anneals in the temperature range from room temperature to 120 degr
eesC, gradually. (C) 2001 Elsevier Science Ltd. All rights reserved.