Thermochemistry of solution of porphyrins of the proto group in mixed organic solvents

Authors
Chernova, OM Berezin, MB
Citation
Om. Chernova et Mb. Berezin, Thermochemistry of solution of porphyrins of the proto group in mixed organic solvents, RUSS J G CH, 70(9), 2000, pp. 1448-1452
Citations number
13
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
70
Issue
9
Year of publication
2000
Pages
1448 - 1452
Database
ISI
SICI code
1070-3632(200009)70:9<1448:TOSOPO>2.0.ZU;2-5
Abstract
Calorimetry at 298 K was used to measure the enthalpies of solution of porp hyrin ligands of the protoporphyrin-IX group in mixed solvents with differe nt physicochemical properties over the entire range of compositions. The ge neral trends in variation of the enthalpy characteristics of solvation of p orphyrins in the nonaqueous solvents studied were discussed.