Conformations of 2-alkyl(aryl)thiocyclohexanones

Authors
Samoshin, VV Kudryavtsev, KB Yartseva, IV Lutsenko, AI Zefirov, NS
Citation
Vv. Samoshin et al., Conformations of 2-alkyl(aryl)thiocyclohexanones, RUSS J ORG, 36(9), 2000, pp. 1279-1281
Citations number
9
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
10704280 → ACNP
Volume
36
Issue
9
Year of publication
2000
Pages
1279 - 1281
Database
ISI
SICI code
1070-4280(200009)36:9<1279:CO2>2.0.ZU;2-5
Abstract
According to the H-1 NMR data, 2-alkyl(aryl)thiocyclohexanones exist mainly as axial conformers. An exception is 2-(2-benzothiazolylthio)cyclohexanone which exists mainly as equatorial conformer due to intramolecular electros tatic interactions.