We present an ionisation model for Polycyclic Aromatic Hydrocarbon (PA
H) molecules from which we determine the various size dependant ionisa
tion states expected in different space environments. Maps of ionisati
on regimes are derived. They allow the estimate of the ionisation frac
tion of PAH for any given set of parameters (electron density, flux fa
ctor and temperature) assuming a typical PAH size of 50 carbon atoms.
Moreover, a particular astronomical case is considered: the variation
in ionisation states with depth in a typical dense cloud illuminated b
y a bright B1.5V star.