Intramolecular alkene hydroaminations catalyzed by simple amido derivatives of the Group 3 metals

Authors
Kim, YK Livinghouse, T Bercaw, JE
Citation
Yk. Kim et al., Intramolecular alkene hydroaminations catalyzed by simple amido derivatives of the Group 3 metals, TETRAHEDR L, 42(16), 2001, pp. 2933-2935
Citations number
8
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
16
Year of publication
2001
Pages
2933 - 2935
Database
ISI
SICI code
0040-4039(20010416)42:16<2933:IAHCBS>2.0.ZU;2-X
Abstract
Bis(trimethylsilyl) amides of the type Ln[N(TMS)(2)](3) have been found to be competent catalysts for representative intramolecular alkene hydroaminat ions. The catalytic cyclization of an aminodiene proceeds in a stepwise man ner to provide the corresponding monocycle and bicycle in a highly stereoco ntrolled manner. (C) 2001 Elsevier Science Ltd. All rights reserved.