Enantioselective allylation of the alpha-sulfonyl radical controlled by coordination of a chiral Lewis acid to an enantiotopic sulfonyl oxygen

Authors
Watanabe, Y Mase, N Furue, R Toru, T
Citation
Y. Watanabe et al., Enantioselective allylation of the alpha-sulfonyl radical controlled by coordination of a chiral Lewis acid to an enantiotopic sulfonyl oxygen, TETRAHEDR L, 42(16), 2001, pp. 2981-2984
Citations number
38
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
16
Year of publication
2001
Pages
2981 - 2984
Database
ISI
SICI code
0040-4039(20010416)42:16<2981:EAOTAR>2.0.ZU;2-7
Abstract
Selective coordination of a chiral Lewis acid to an enantiotopic sulfonyl o xygen enabled enantioselective allylation of the alpha -sulfonyl radical. T he addition-allylation products were obtained in low to good stereoselectiv ities (up to 84% eel. (C) 2001 Elsevier Science Ltd. All rights reserved.