A novel 7(6 -> 2)abeoabietane-type diterpene, obtusanal, from the Heartwood of Clamaecyparis obtusa var. formosana

Authors
Kuo, YH Chen, CH
Citation
Yh. Kuo et Ch. Chen, A novel 7(6 -> 2)abeoabietane-type diterpene, obtusanal, from the Heartwood of Clamaecyparis obtusa var. formosana, TETRAHEDR L, 42(16), 2001, pp. 2985-2986
Citations number
4
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
16
Year of publication
2001
Pages
2985 - 2986
Database
ISI
SICI code
0040-4039(20010416)42:16<2985:AN7-2D>2.0.ZU;2-E
Abstract
A novel 7(6 -->2)abeoabietane-type diterpene, obtusanal (1), together with a known 12-hydroxy-6,7-secoabieta-8,11,13-triene-6,7-dial (2) isolated from the heartwood of Chamnecyparis obtusa var. formosana, were elucidated on t he basis of 2D-NMR data. The biosynthesis of 1 was proposed deriving from 1 2-hydroxy-3-oxo-6,7-secoabieta-8,11,13-triene-6,7-dial (6) via aldol conden sation. (C) 2001 Elsevier Science Ltd. All rights reserved.