S. Frere et al., Microwave acceleration of the Pechmann reaction on graphite/montmorillonite K10: application to the preparation of 4-substituted 7-aminocoumarins, TETRAHEDR L, 42(15), 2001, pp. 2791-2794
Efficient synthesis of 7-aminocoumarins was performed via the Pechmann reac
tion by microwave irradiation of the reactants on solid support (graphite/m
ontmorillonite K10). In this convenient new methodology, the strong thermal
effect due to graphite/microwaves interaction is associated with the acidi
c catalyst role of the clay. (C) 2001 Elsevier Science Ltd. All rights rese
rved.