Microwave acceleration of the Pechmann reaction on graphite/montmorillonite K10: application to the preparation of 4-substituted 7-aminocoumarins

Citation
S. Frere et al., Microwave acceleration of the Pechmann reaction on graphite/montmorillonite K10: application to the preparation of 4-substituted 7-aminocoumarins, TETRAHEDR L, 42(15), 2001, pp. 2791-2794
Citations number
17
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
15
Year of publication
2001
Pages
2791 - 2794
Database
ISI
SICI code
0040-4039(20010409)42:15<2791:MAOTPR>2.0.ZU;2-F
Abstract
Efficient synthesis of 7-aminocoumarins was performed via the Pechmann reac tion by microwave irradiation of the reactants on solid support (graphite/m ontmorillonite K10). In this convenient new methodology, the strong thermal effect due to graphite/microwaves interaction is associated with the acidi c catalyst role of the clay. (C) 2001 Elsevier Science Ltd. All rights rese rved.