The changing forms and concentrations of arsenic through aluminium-based co
agulation treatment processes were tracked for three drinking-water treatme
nt plants. This has provided direct evidence of where and how arsenic is re
moved. In general, soluble As(V) is converted to particulate As(V) by adsor
ption during rapid mixing, and is removed along with naturally occurring pa
rticulate arsenic predominantly by clarification. Soluble As(III) tracks th
rough the treatment processes and is converted to soluble As(V) during fina
l chlorination. The ability of a water treatment process to achieve the max
imum acceptable concentration for arsenic in drinking water is dependent on
the concentration of As(III) in the source water. (C) 2001 Elsevier Scienc
e Ltd. All rights reserved.