Coordination chemistry of P-rich phosphanes and silylphosphanes. XXII - The formation of [eta(2)-{Bu-t-P=P-SiMe3}Pt(PR3)(2)] from (Me3Si)(BuP)-Bu-t-P=P(Me)Bu-t(2) and [eta(2)-(C2H4)Pt(PR3)(2)]

Authors
Krautscheid, H Matern, E Olkowska-Oetzel, J Pikies, J Fritz, G
Citation
H. Krautscheid et al., Coordination chemistry of P-rich phosphanes and silylphosphanes. XXII - The formation of [eta(2)-{Bu-t-P=P-SiMe3}Pt(PR3)(2)] from (Me3Si)(BuP)-Bu-t-P=P(Me)Bu-t(2) and [eta(2)-(C2H4)Pt(PR3)(2)], Z ANORG A C, 627(4), 2001, pp. 675-678
Citations number
8
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
627
Issue
4
Year of publication
2001
Pages
675 - 678
Database
ISI
SICI code
0044-2313(200103)627:4<675:CCOPPA>2.0.ZU;2-M
Abstract
(Me3Si)(BuP)-Bu-t-P= P(Me)Bu-t(2) reacts with [eta (2)- (C2H4}Pt(PR3)(2)] y ielding [eta (2)-{Bu-t-P=P-SiMe3}Pt(PR3)(2)] However, there is no indicatio n for an isomer which would be the analogue to the well known [eta (2)-{(Bu 2P)-Bu-t-P)Pt(PPh3)(2)]. The syntheses and NMR data of [eta (2)-{Bu-t-P=P-S iMe3}Pt(PPh3)(2)] and [eta (2)-{Bu-t-P=P-SiMe3}Pt(PMe3)(2)] as well as the results of the single crystal structure determination of [eta (2)-{Bu-t-P=P -SiMe3}Pt(PPh3)(2)] are reported.