Rb4Mo21Se24 containing Mo-12 and Mo-15 clusters

Authors
Picard, S Gougeon, P Potel, M
Citation
S. Picard et al., Rb4Mo21Se24 containing Mo-12 and Mo-15 clusters, ACT CRYST C, 57, 2001, pp. 335-336
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
4
Pages
335 - 336
Database
ISI
SICI code
0108-2701(20010415)57:<335:RCMAMC>2.0.ZU;2-H
Abstract
Rubidium molybdenum selenide, Rb4Mo21Se24, crystallizes in the trigonal spa ce group R(3) over bar $. Its crystal structure consists of a mixture of Mo 12Se14Se6 and Mo15Se17Se6 cluster units in a 1:2 ratio. Both units are inte rconnected through Mo-Se bonds. The Rb+ cations occupy large voids between the different cluster units.