Bis(2,2-bipyridine-N,N ')tetra-mu-chloro-tetracopper(I)

Authors
Cui, Y Chen, JT Chen, G Ren, J Yu, WC Qian, YT
Citation
Y. Cui et al., Bis(2,2-bipyridine-N,N ')tetra-mu-chloro-tetracopper(I), ACT CRYST C, 57, 2001, pp. 349-351
Citations number
18
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
4
Pages
349 - 351
Database
ISI
SICI code
0108-2701(20010415)57:<349:B'>2.0.ZU;2-O
Abstract
A novel centrosymmetric chair-like dimer, bis(2,2'-bipyridine)-1 kappa N-2, N';3 kappa N-2,N'-tetra-mu -chloro-1:2 kappa 2Cl;2:3 kappa Cl-2;3:4 kappa ( 2)-Cl;1:4 kappa Cl-2-tetracopper(I), [Cu4Cl4(C10H8N2)(2)], has been solvoth ermally synthesized and structurally characterized. The complex self-assemb les into a three-dimensional network via C-H . . . Cl hydrogen bonds, pi-pi stacking and weak Cu . . . Cl electrostatic interactions.