{Bis[2-(2-oxido-1-naphthylmethylideneamino)phenyl] disulfide}chloroiron(III)

Authors
Elmali, A Elerman, Y Svoboda, I
Citation
A. Elmali et al., {Bis[2-(2-oxido-1-naphthylmethylideneamino)phenyl] disulfide}chloroiron(III), ACT CRYST C, 57, 2001, pp. 375-376
Citations number
22
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
4
Pages
375 - 376
Database
ISI
SICI code
0108-2701(20010415)57:<375:{D>2.0.ZU;2-S
Abstract
The crystal structure of the title compound, {bis[2-(2-oxido-2-naphthyliden eamino)phenyl] disulfide-kappa O-5,N,S,N',O'}chloro-iron(III), [FeCl(C34H22 N2O2S2)], has been determined. The structure consists of monomeric iron(III ) complexes with distorted octahedral coordination. The disulfide functions as a pentadentate ligand and the Fe-III atom is coordinated through two N, two O and one S atom, and one chloride ion. The distance between the secon d S atom and the Fe-III atom is a non-bonding 3.8473 (14) Angstrom.