Drastically improved photooxidation efficiencies, when compared to bulk WO3
, are obtained with nanocrystalline WO3 films (see Figure) deposited from a
colloidal solution of tungstic acid. Saturation of the photocurrent, which
occurs even for moderate potential differences, indicates a completely dif
ferent mechanism of charge separation. The electrodes should be highly effe
ctive for photoelectrolysis of water by sunlight.
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