Catalytic oxidation of 1-hexene with molecular oxygen by the Cu(CH3CN)(2)(NO2)(2)/Pd(CH3CN)(2)Cl-2 bimetallic system

Authors
Castillo, A Baricelli, PJ Pardey, AJ Moya, SA
Citation
A. Castillo et al., Catalytic oxidation of 1-hexene with molecular oxygen by the Cu(CH3CN)(2)(NO2)(2)/Pd(CH3CN)(2)Cl-2 bimetallic system, BOL SOC CH, 46(1), 2001, pp. 3-8
Citations number
19
Categorie Soggetti
Chemistry
Journal title
BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA
ISSN journal
03661644 → ACNP
Volume
46
Issue
1
Year of publication
2001
Pages
3 - 8
Database
ISI
SICI code
0366-1644(200103)46:1<3:COO1WM>2.0.ZU;2-L
Abstract
This work describes the study of the oxidation reaction of l-hexene to oxyg enated compounds homogeneous catalyzed by the bimetallic system, Cu(CH3CN)( 2)(NO2)(2)I Pd(CH3CN)(2)CI2 dissolved in acetonitrile/chloroform under oxyg en pressure (1-20 atm) at 55-100 degreesC. The results show that 2-hexanone and 3-hexanone are the only oxygenated products formed at 55 degreesC. Oth er oxygenated products such as 2-methyl-3-propyl-oxyrane, 2,3-diethyl-oxyra ne and butyl-oxyrane were also observed, beside of the above mentioned at t emperatures higher than 55 degreesC.