Effect of epoxidation of carbocyclic double bonds on conformational flexibility of 1(10)E,4E-germacranolides

Authors
Kaldybaeva, AK Edil'baeva, TT Turdybekov, KM
Citation
Ak. Kaldybaeva et al., Effect of epoxidation of carbocyclic double bonds on conformational flexibility of 1(10)E,4E-germacranolides, CHEM NAT CO, 36(5), 2000, pp. 497-500
Citations number
20
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
CHEMISTRY OF NATURAL COMPOUNDS
ISSN journal
00093130 → ACNP
Volume
36
Issue
5
Year of publication
2000
Pages
497 - 500
Database
ISI
SICI code
0009-3130(200009/10)36:5<497:EOEOCD>2.0.ZU;2-C
Abstract
The effect of substitution of double bonds by epoxy groups in 1(10)E,4E-ger macranolides is studied by molecular mechanics. The probabilities of formin g conformers in the epoxy derivatives are determined Barriers to possible c onformational transitions are estimated.