We report on the high-pressure synthesis and superconductivity of MgB2 inte
rmetallic compounds. The compounds have been obtained through high-pressure
sintering of the mixtures of magnesium and boron fine powders under 5.0 GP
a and at similar to 1000 degreesC for 30 min. Magnetic measurements using a
SQUID magnetometer show the sharp bulk superconducting transition above 39
K; the four-probe de resistivity measurements indicate the highly-conducti
ve normal state and sharp superconducting transition. The results highlight
that high-pressure synthesis would be a promising way to promote the studi
es of this new kind of intermetallic superconductors.