Electrochromic properties of NiO-based thin films prepared by sol-gel and dip coating

A new method for chemical deposition of NiOxHy-based films was developed. T he films obtained have electrochromic properties and good adhesion to the s ubstrate. The precursor sol consists of an alcoholic solution of NiCl2 and Ti alcoxide. Films deposited on indium-tin-oxide substrates were prepared b y dip coating. The electrochromic efficiency of thin films prepared under d ifferent conditions was determined. We report on the effects of (a) Ni conc entration, (b) Ti content and (c) temperature of firing on the electrochrom ic efficiency. Electrochromic efficiencies measured at lambda= 632.8 nm of films with different thicknesses ( similar to 100-200 nm) range from 10 to 42 cm(2) C (- 1), with a variation in transmittance up to 30%. The colourin g response time is strongly dependent on Ti content. For Ti-doped films thi s time is 5-80 times longer than for undoped ones. The variations in monoch romatic transmittance during voltammetric cycles suggest that all the elect ric charge consumed by redox reactions is involved in the colouring process . (C) 2001 Elsevier Science Ltd. All rights reserved.