The analysis of the carbonate-calcium system in a wide range of steppe soil
s, including irrigated soils, has been performed. it is shown that the stat
e of this system is mainly controlled by geochemical flows inside soil comb
inations and complexes, as well as by local peculiarities of environmental
conditions. Usually, the solutions of steppe soils are supersaturated with
respect to calcite. Several types of carbonate-calcium equilibrium can be d
istinguished in steppe soils. The combined analysis of morphological, chemi
cal, and thermodynamic data makes it possible to suggest a general scheme o
f the state of soil carbonates.