TiO2-doped vanadium dioxide films have been deposited from vanadium ox
o-alkoxide solutions. VO2 thin films of good optical quality are obtai
ned after heating at 500 degrees C under a reducing atmosphere. These
films exhibit highly reversible electrical and optical switching aroun
d 70 degrees C. A hysteresis phenomenon is observed, but V1-xTixO2 fil
ms do not exhibit the same behavior as other doped VO2 films. The widt
h of the hysteresis curve decreases as soon as Ti is added to the VO2
film. Best switching characteristics are obtained with Ti approximate
to 5%. Evidence of the coexistence of two phases around the transition
temperature is presented. (C) 1997 Elsevier Science Ltd.