H3N(CH2)(3)NH3 center dot Zn(HPO3)(2) containing four-ring chains of ZnO4 tetrahedra and HPO3 pseudo pyramids

Authors
Harrison, WTA
Citation
Wta. Harrison, H3N(CH2)(3)NH3 center dot Zn(HPO3)(2) containing four-ring chains of ZnO4 tetrahedra and HPO3 pseudo pyramids, INT J INORG, 3(2), 2001, pp. 187-189
Citations number
13
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
INTERNATIONAL JOURNAL OF INORGANIC MATERIALS
ISSN journal
14666049 → ACNP
Volume
3
Issue
2
Year of publication
2001
Pages
187 - 189
Database
ISI
SICI code
1466-6049(200103)3:2<187:HCDZCF>2.0.ZU;2-K
Abstract
The solution-mediated synthesis and single-crystal structure of H3N(CH2)(3) NH3. Zn(HPO3)(2) are reported. This phase is built up from chains of vertex -linked ZnO4 and HPO3 building units crosslinked by 1,3-diammonium propane cations. The relationship of the title compound to known zinc phosphate pha ses is briefly discussed. Crystal data for H3N(CH2)(3)NH3. Zn(HPO3)(2): ZnP 2O6N2C3H14, M-r=301.49, ortholhombic, Pbcm (No. 57), a=8.6924 (4) Angstrom, b=7.8926 (4) Angstrom, c=16.6224 (8) Angstrom, V=1140.4 (2) Angstrom (3), Z=4, rho (calc)=1.756 g/cm(3), mu =24.4 cm(-1), T=298 (2) K, R=0.025, R-w=0 .037 (calculated w(i)). (C) 2001 Elsevier Science Ltd. AH rights reserved.