Capillary adhesion has been pointed out to be an important mechanism contro
lling the properties and behaviour of medium-particle-size dispersed materi
al. A generalised method for calculation meniscus curvature radii of liquid
bridge formed between powder particles as a result of water vapour condens
ation has been given. The obtained relationships will be a basis for capill
ary adhesion force calculations and for estimation of the effect of relativ
e humidity of surrounding atmosphere on the forces. A complete analysis of
the meniscus radii has been accomplished for all important contact configur
ation systems existing in powders. On this basis hypotheses concerning the
values and trends of adhesion forces in powders have been proposed.