C-3-SYMMETRICAL CHIRAL AMIDATE COMPLEXES - EFFECTS OF LIGAND-BINDING ON CAVITY STRUCTURE

Authors
HAMMES BS RAMOSMALDONADO D YAP GPA LIABLESANDS L RHEINGOLD AL YOUNG VG BOROVIK AS
Citation
Bs. Hammes et al., C-3-SYMMETRICAL CHIRAL AMIDATE COMPLEXES - EFFECTS OF LIGAND-BINDING ON CAVITY STRUCTURE, Inorganic chemistry, 36(15), 1997, pp. 3210
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
36
Issue
15
Year of publication
1997
Database
ISI
SICI code
0020-1669(1997)36:15<3210:CCAC-E>2.0.ZU;2-9
Abstract
A new homochiral tripodal ligand -(S)-(-)-(alpha)-methylbenzylcarbomoy lmethyl)amine (H(3)1(S-mbz)) is reported, along with the preparation a nd structural characterization of two metal complexes K[Zn1(S-mbz)] an d K[Fe1(S-mbz)(NO)]. Significant changes in cavity structure are obser ved upon binding external ligands.