Effects of the diffusion layer characteristics on the performance of polymer electrolyte fuel cell electrodes

Several carbon blacks and graphite were investigated as candidates for diff usion layer preparation in polymer electrolyte fuel cell electrodes (PEFC). Single cell electrochemical characterizations under different working cell conditions were carried out on the electrodes by varying the kind of carbo n in the diffusion layer. An improvement in cell performance was found by u sing Shawinigan Acetylene Black (SAB) as carbon, resulting in a measured po wer density of about 360 mW cm(-2) in H-2/air operation at 70 degreesC and 1/1 bar. Pore size distribution and scanning electron microscopy analyses w ere carried out to help the understanding of the different behaviour of the investigated carbon diffusion layers.