Piezoelectric response nonlinearity is approached using the Preisach descri
ption of hysteretic systems as collection of distributed bistable units. Th
e Preisach model and its recent physical interpretation in terms of moving
domain wall in a stochastically described pinning field are reviewed. It is
shown that such an approach can effectively render not only the piezoelect
ric coefficient field dependences but also the field-response hysteresis, e
specially in the well-known case of linear piezoelectric field dependence (
i.e., Rayleigh's law) where the bistable units are distributed homogeneousl
y. New expressions for piezoelectric nonlinear behavior departing from the
classical linear dependence are then derived using a more complex distribut
ion and are qualitatively compared to experimental data for piezoelectric m
aterials as varied as lead titanate, strontium bismuth titanate, and lead z
irconate titanate. Finally, these expressions are shown to be adequate for
the description of various piezoelectric coefficient behaviors such as: pol
ynomial dependence on the applied field, dc field effect on nonlinear contr
ibutions, and threshold field for nonlinearity. (C) 2001 American Institute
of Physics.