NEW SYNTHESIS ROUTES TO LITHIUM AND CESIUM CYANIDE SALTS

Authors
MARKLEY TJ TOBY BH PEARLSTEIN RM RAMPRASAD D
Citation
Tj. Markley et al., NEW SYNTHESIS ROUTES TO LITHIUM AND CESIUM CYANIDE SALTS, Inorganic chemistry, 36(15), 1997, pp. 3376
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
36
Issue
15
Year of publication
1997
Database
ISI
SICI code
0020-1669(1997)36:15<3376:NSRTLA>2.0.ZU;2-W
Abstract
New simple synthesis routes for two alkali cyanide salts, LiCN, and Cs CN have been demonstrated. A crystal structure of LiCN . 0.6DMF . 0.4D MAc was obtained. The structure can be described as infinite sheets of Li pairs, linked end-on by cyanide ligands. The Li atoms are bridged above and below the sheet by a DMF or DMAc oxygen atom.