Vibrational de-excitation of v=1 H-2 during collisions with a Cu(100) surface

The dynamics of vibrational de-excitation of v=1 H-2 on a Cu(100) surface i s studied using a six-dimensional quantum wave packet method. The de-excita tion probability increases with increasing collision energy and initial mol ecular rotational quantum number, j. A strong dependence on molecular orien tation is found with molecules rotating with helicoptering motion (m(j)=j) exhibiting larger de-excitation probabilities, in general, than those with cartwheeling motion (m(j)=0). The final j-state distribution and quadrupole alignment are computed as functions of collision energy. The competition b etween vibrational de-excitation and other dynamic processes during the col lision is analyzed. The total de-excitation probability is in good agreemen t with vibrational inelasticities from experiment but the calculations over estimate the population of scattered H-2 in (v=0, j) for large j. (C) 2001 American Institute of Physics.