K. Lebbou et al., Effect of gadolinium (Gd3+) addition on the monophased field and crystal growth of Ba2NaNb5O15 (BNN), J CRYST GR, 224(1-2), 2001, pp. 59-66
Ba2Na1-3xGdxNb5O15 compounds with (0.02 less than or equal tox less than or
equal to0.2) have been prepared. The limit of the monophased composition f
ield was determined as a function of Gd substitution. The effect of Gd on b
arium sodium niobate (BNN) was examined by X-ray powder diffraction at room
temperature as a function of temperature. The melt behavior was studied by
DTA. The homogeneity of single-crystal fibers doped with Gd and grown by m
icro-pulling down technique was investigated by EPMA. No cracks or other in
homogeneities could be detected, as already shown for Yb- and Nd-doped BNN.
In this study, Gd addition was effective for growth of bulk crystals by Cz
ochralski technique. (C) 2001 Elsevier Science B.V. All rights reserved.